Coal combustion byproducts (CCBs) are considered
to be four distinct and extremely different materials.
FLY ASH
Fly ash is the finest of coal ash particles.
It is called "fly" ash because it is transported from
the combustion chamber by exhaust gases. Fly ash is the fine powder
formed from the mineral matter in coal, consisting of the noncombustible
matter in coal plus a small amount of carbon that remains from incomplete
combustion. Fly ash is generally light tan in color and consists
mostly of silt-sized and clay-sized glassy spheres. This gives fly
ash a consistency somewhat like talcum powder. Properties of fly
ash vary significantly with coal composition and plant-operating
conditions.
Fly ash can be referred to as either cementitious
or pozzolanic. A cementitious material is one that hardens when
mixed with water. A pozzolanic material will also harden with water
but only after activation with an alkaline substance such as lime.
These cementitious and pozzolanic properties are what make some
fly ashes useful for cement replacement in concrete and many other
building applications.
BOTTOM
ASH
Coal bottom ash and
fly ash are quite different physically, mineralogically, and chemically.
Bottom ash is a coarse, granular, incombustible byproduct that is
collected from the bottom of furnaces that burn coal for the generation
of steam, the production of electric power, or both. Bottom ash is
coarser than fly ash, with grain sizes spanning from fine sand to
fine gravel. The type of byproduct produced depends on the type of
furnace used to burn the coal.
BOILER SLAG
Boiler slag is coarser
than conventional fly ash and is formed in cyclone boilers, which
produce a molten ash that is cooled with water. Boiler slag is generally
a black granular material with numerous engineering uses.
FGD GYPSUM
Flue gas desulfurization (FGD) gypsum
is also known as scrubber gypsum. FGD gypsum is the byproduct of an
air pollution control system that removes sulfur from the flue gas
in calcium-based scrubbing systems. It is produced by employing forced
oxidation in the scrubber and is composed mostly of calcium sulfate.
FGD gypsum is most commonly used for agricultural purposes and for
wallboard production.